Zircon crystals from Western Australia's Jack Hills region crystallized 4.4 billion years ago, building on earlier studies that used lead isotopes to date Australian zircons and identify them as the oldest bits of the Earth's crust. The microscopic zircon crystal is now confirmed to be the oldest known material of any kind formed on Earth. 

A new study strengthens the theory of a "cool early Earth," where temperatures were low enough for liquid water, oceans and a hydrosphere not long after the planet's crust congealed from a sea of molten rock. The study reinforces the belief that Earth had a hydrosphere before 4.3 billion years ago and possibly life not long afte.

Writing in Nature Geoscience, an international team of researchers led by University of Wisconsin-Madison geoscience Professor John Valley confirms that the Earth's crust first formed at least 4.4 billion years ago, just 160 million years after the formation of our solar system. The work shows that the time when our planet was a fiery ball covered in a magma ocean came earlier.

The study was conducted using atom-probe tomography that, in conjunction with secondary ion mass spectrometry, permitted the scientists to accurately establish the age and thermal history of the zircon by determining the mass of individual atoms of lead in the sample. Instead of being randomly distributed in the sample, as predicted, lead atoms in the zircon were clumped together, like "raisins in a pudding," notes Valley. 

The clusters of lead atoms formed 1 billion years after crystallization of the zircon, by which time the radioactive decay of uranium had formed the lead atoms that then diffused into clusters during reheating. "The zircon formed 4.4 billion years ago, and at 3.4 billion years, all the lead that existed at that time was concentrated in these hotspots," Valley says. "This allows us to read a new page of the thermal history recorded by these tiny zircon time capsules."

The formation, isotope ratio and size of the clumps — less than 50 atoms in diameter — become, in effect, a clock, says Valley, and verify that existing geochronology methods provide reliable and accurate estimates of the sample's age. In addition, Valley and his group measured oxygen isotope ratios, which give evidence of early homogenization and later cooling of the Earth.

"The Earth was assembled from a lot of heterogeneous material from the solar system," Valley explains, noting that the early Earth experienced intense bombardment by meteors, including a collision with a Mars-sized object about 4.5 billion years ago "that formed our moon, and melted and homogenized the Earth. Our samples formed after the magma oceans cooled and prove that these events were very early."