Previously, only amorphous polymer materials approached such levels of performance. On the other hand, these “gigantic respiration” and their respiration, which takes place at constant overall shape, is reversible. This discovery, of interest for numerous industrial applications, is published in the journal Science on March 30, 2007.
Structure of chromium (III) diphenyl dicarboxylate, one of the gigantic respiration crystalline solids, in its crude form following synthesis (middle), with all traces of solvent removed (on the left), and after absorption of solvent and increase in volume (on the right).
Credit: G. Ferey - CNRS 2007